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Sp hybridization is used to describe ethylene (acetylene) molecule. In order to establish a bond between the carbon atoms, two sp orbitals are overlapped to form a σ-bond and then the remaining four non-hybrid p-orbitals are overlapped to form two π-bonds (the distribution of the π-bonds electrons forms a cylindrical structure around the bond). A triple bond is formed by one σ-bond and two π-bonds.
When a bond is formed between the carbon atom and the hydrogen atom, sp and s-orbital are overlapped to form the σ-bonds (simple bonds are formed).
